Synthesis of nanophase tungsten carbide by electrical discharge machining

Tungsten carbide nanopowders were synthesized successfully by electric discharge machining followed by annealing under a nitrogen atmosphere. The tungsten workpieces were initially melted and evaporated on the working surface during the electric discharge machining process, and then the tungsten powders were reacted with the carbon electrode and the working medium of kerosene to form the nanocrystalline WC_1−x powders. The powders produced were characterized by XRD, SEM, and TEM. When annealing the powders under an N₂ atmosphere, the cubic phases of WC_1−x gradually changed to hexagonal W₂C and then were transformed fully to nanocrystalline hexagonal WC at 1200 °C, with the nanocrystalline tungsten carbide encapsulated in a carbon shell. On the other hand, under an H₂ atmosphere, the WC_1−x phase changed via a W₂C phase to reduced powders of pure tungsten at 1000 °C or were reduced directly from WC_1−x to elemental W.     

Dependence of Silicon Carbide Product Morphology on the Degree of Mechanical Activation

Mechanical activation before carbothermic reduction can substantially enhance the formation of SiC from SiO₂and carbon mixtures. However, the morphology (e.g., particles or whiskers) of SiC formed from mechanically activated SiO₂and carbon mixtures is dependent of the degree of mechanical activation and the condition of the subsequent carbothermic reduction. These phenomena are investigated and rationalized based on the increased reactivity of the reactants and SiC formation mechanisms.     

Film morphology and reaction rate for the CVD of tungsten by the WF6—SiH4 reaction

Journal of Electronic Materials - Low pressure chemical vapor deposition (LPCVD) of tungsten (W) by SiH4 reduction of WF6 on Si(100) surfaces was studied in a single-wafer, cold-wall reactor over a...     

2006年中国钨工业发展报告

综述了2006年我国钨工业发展现状,分析了钨工业经济运行的政策环境、产业结构、市场供需、竞争态势,指出了当前钨工业发展中的几个突出问题,并提出了相应的对策建议。     

Service Reliability Assessment of Weld Repaired CrMoV Steel Rotors

This research deals with the service evaluation of a retired CrMoV steel rotor that has been repaired using deep groove multi‐pass submerged arc welding (SAW) and gas tungsten arc welding (GTAW). Accelerated creep tests were conducted at several elevated temperatures and extrapolated to the service temperatures. The coalescence of carbides and cavity growth during creep were evaluated. For the CrMoV‐GTAW samples, it was found that the creep life depended on the location of the crossweld in the welded specimen. The service lives of the weldments were extrapolated.     

提高硬质合金工具使用寿命的研究

通过改变硬质合金剩余应力类型和状态，改善了硬质合金的性能，提高了硬质合金工具的使用寿命。     

95W-Ni-Fe 合金工艺缺陷的 SAM 和 XPS 分析

藉助扫描俄歇探针、Ｘ射线光电子谱等分析了９５Ｗ－Ｎｉ－Ｆｅ合金碳污染和氧化的本质。发现，碳污染试样中碳的化学状态主要为石墨，少量为铁或镍的有机化合物，这些物质的界面富集使材料脆化。钨合金氧化后，氧大量富集于钨／粘结相界面，使沿着该界面的断裂更容易发生。     

凸轮的表面裂纹分析

本文对一凸轮的表面裂纹进行了分析。渗碳后表层残余奥氏体含量过高级网状碳化物导致该凸轮在精磨过程中出现了磨削裂纹，本文还提出了二次回火或冰冷处理等改进措施来防止磨削裂纹的产生。     

Effect of RE on Granulation of Eutectic Carbide in Ledeburite Steel

ＲｅｃｅｎｔｌｙｔｈｅｂｅｎｅｆｉｃｉａｌａｃｔｉｏｎｓｏｆＲＥｏｎｉｒｏｎａｎｄｓｔｅｅｌｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄａｒｏｕｎｄｔｈｅｗｏｒｌｄ．ＲＥｃａｎｎｏｔｏｎｌｙｄｅｏｘｉｄｉｚｅａｎｄｄｅｓｕｌｐｈｕｒｉｚｅｔｈｅｍｅｌｔａｎｄｆ...     

快速钨铼热电偶的测温误差

本文用热电偶误差计算的通用方法（极限误差表达法）分析了构成快速钨铼热电偶测温误差的因素，从量的角度探讨了各因素对总的误差的影响，对如何认识快速钨铼热电偶的测温精度，提出了可供参考的观点。